Spectroscopy is the basic tool for studying molecular physics and realizing biochemical sensing. However, it is challenging to realize sub-femtometer resolution spectroscopy over broad bandwidth. Broadband and high-resolution spectroscopy with calibrated optical frequency is demonstrated by bridging the fields of speckle pattern and electro-optic frequency comb. A wavemeter based on a whispering-gallery-mode barcode is proposed to link the frequencies of a probe continuous-wave laser and an ultrastable laser. The ultrafine electro-optic comb lines are generated from the probe laser to record spectrum of sample with sub-femtometer resolution. Measurement bandwidth is a thousandfold broader than comb bandwidth, by sequentially tuning the probe laser while its wavelength is determined. This approach fully exploits the advantages of two fields to realize 0.8-fm resolution with a fiber laser and 80-nm bandwidth with an external cavity diode laser. The spectroscopic measurements of an ultrahigh Q-factor cavity and gas molecular absorption are experimentally demonstrated. The compact system, predominantly constituted by few-gigahertz electronics and telecommunication components, shows enormous potential for practical spectroscopic applications.

Optical frequency comb with evenly spaced lines over a broad bandwidth has revolutionized the fields of optical metrology and spectroscopy. Here, we propose a fast interleaved dual-comb spectroscopy with sub-femtometer-resolution and absolute frequency, in which two electro-optic frequency combs are swept. Electrically-modulated stabilized laser enables ultrahigh resolution of 0.16 fm (or 20 kHz in optical frequency) and single-shot measurement in 90 ms. Total 20 million points are recorded spanning 3.2 nm (or 400 GHz) bandwidth, corresponding to a spectral sampling rate of 2.5 × 10⁸ points/s under Nyquist-limitation. Besides, considering the trade-off between the measurement time and spectral resolution, a fast single-shot measurement is also realized in 1.6 ms with 8 fm (or 1 MHz) resolution. We demonstrate the 25-averaged result with 30.6 dB spectral measurement signal-to-noise ratio (SNR) by reducing the filter bandwidth in demodulation. The results show great prospect for precise measurement with flexibly fast refresh time, high spectral resolution, and high SNR.Optical frequency comb with evenly spaced lines over a broad bandwidth has revolutionized the fields of optical metrology and spectroscopy. Here, we propose a fast interleaved dual-comb spectroscopy with sub-femtometer-resolution and absolute frequency, in which two electro-optic frequency combs are swept. Electrically-modulated stabilized laser enables ultrahigh resolution of 0.16 fm (or 20 kHz in optical frequency) and single-shot measurement in 90 ms. Total 20 million points are recorded spanning 3.2 nm (or 400 GHz) bandwidth, corresponding to a spectral sampling rate of 2.5 × 10⁸ points/s under Nyquist-limitation. Besides, considering the trade-off between the measurement time and spectral resolution, a fast single-shot measurement is also realized in 1.6 ms with 8 fm (or 1 MHz) resolution. We demonstrate the 25-averaged result with 30.6 dB spectral measurement signal-to-noise ratio (SNR) by reducing the filter bandwidth in demodulation. The results show great prospect for precise measurement with flexibly fast refresh time, high spectral resolution, and high SNR.